A History of Science

第20章

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第20章

A History of Science Henry Smith Williams

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A History of Science
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  Volta’sannouncementofhispilewasscarcelytwomonthsoldwhentwoEnglishmen,Messrs。NicholsonandCarlisle,madethediscoverythatthecurrentfromthegalvanicbatteryhadadecidedeffectuponcertainchemicals,amongotherthingsdecomposingwaterintoitselements,hydrogenandoxygen。OnMay7,1800,theseinvestigatorsarrangedtheendsoftwobrasswiresconnectedwiththepolesofavoltaicpile,composedofalternatesilverandzincplates,sothatthecurrentcomingfromthepilewasdischargedthroughasmallquantityof\"NewRiverwater。\"\"A

  finestreamofminutebubblesimmediatelybegantoflowfromthepointofthelowerwireinthetubewhichcommunicatedwiththesilver,\"wroteNicholson,\"andtheoppositepointoftheupperwirebecametarnished,firstdeeporangeandthenblack……\"Theproductofgasduringtwohoursandahalfwastwo-

  thirtiethsofacubicinch。\"Itwasthenmixedwithanequalquantityofcommonair,\"continuesNicholson,\"andexplodedbytheapplicationofalightedwaxenthread。\"

  Thisdemonstrationwasthebeginningoftheveryimportantscienceofelectro-chemistry。

  TheimportanceofthisdiscoverywasatoncerecognizedbySirHumphryDavy,whobeganexperimentingimmediatelyinthisnewfield。Heconstructedaseriesofbatteriesinvariouscombinations,withwhichheattackedthe\"fixedalkalies,\"thecompositionofwhichwasthenunknown。Veryshortlyhewasabletodecomposepotashintobrightmetallicglobules,resemblingquicksilver。Thisnewsubstancehenamed\"potassium。\"Theninrapidsuccessiontheelementarysubstancessodium,calcium,strontium,andmagnesiumwereisolated。

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